Verification of the Laser Powder Bed Fusion Performance of 2024 Aluminum Alloys Modified Using Nano-LaB6

The application of 2024 aluminum alloy (comprising aluminum, copper, and magnesium) in the aerospace industry is extensive, particularly in the manufacture of seats. However, this alloy faces challenges during laser powder bed fusion (PBF-LB/M) processing, which often leads to solidification and cracking issues. To address these challenges, LaB6 nanoparticles have been investigated as potential grain refiners. This study systematically examined the impact of adding different amounts of LaB6 nanoparticles (ranging from 0.0 to 1.0 wt.%) on the microstructure, phase composition, grain size, and mechanical properties of the composite material. The results demonstrate that the addition of 0.5 wt.% LaB6 significantly reduces the average grain size from 10.3 μm to 9 μm, leading to a significant grain refinement effect. Furthermore, the tensile strength and fracture strain of the LaB6-modified A2024 alloy reach 251 ± 2 MPa and 1.58 ± 0.12%, respectively. These findings indicate that the addition of appropriate amounts of LaB6 nanoparticles can effectively refine the grains of 2024 aluminum alloy, thereby enhancing its mechanical properties. This discovery provides important support for the broader application of 2024 aluminum alloy in the aerospace industry and other high-performance fields.


Introduction
Laser additive manufacturing technology, specifically laser powder bed fusion (PBF-LB/M), is highly regarded in various technical fields and has found applications in the aerospace, biomedical, automotive, and other industries [1,2].PBF-LB/M technology utilizes a computer-aided design model to efficiently melt successive layers of powdered material with a high-energy laser beam.The molten metals then solidify to create manufacturing components.In comparison to traditional manufacturing methods, PBF-LB/M technology offers advantages such as near-net forming and superior material utilization, allowing for the production of high-density, intricate, and irregularly shaped parts [3,4].
Research indicates that forged aluminum alloys, particularly the 2xxx, 6xxx, and 7xxx series, demonstrate superior strength compared to cast aluminum-silicon alloys [5].A2024 aluminum alloy primarily consists of copper (Cu: 3.8-4.9%),magnesium (Mg: 1.2-1.8%),chromium (Cr: 0.10%), silicon (Si: 0.50%), zinc (Zn: 0.25%), and manganese (Mn: 0.30-1.0%),and is renowned for its high strength and the ability to be strengthened through heat treatment [6].With a favorable strength-density ratio, ductility, and resistance to fatigue fracture under alternating stress, it has become a preferred material for demanding applications where performance is crucial.It has progressively established itself as the primary material for critical aerospace components, including aviation seats and bolts [7][8][9].Nevertheless, the processability of A2024 aluminum alloy using PBF-LB/M technology is considerably limited.This constraint arises from a combination of factors: subpar fluidity; the relatively high degree of the effective reflection of light shining on its surface;

Experimental Procedures 2.1. Materials and Powder Preparation
In this study, the raw material for the A2024 aluminum alloy powder was prepared using the gas atomization method.Table 1 outlines the chemical components of this powder, which exhibit a regular spherical shape and a typical unimodal particle size distribution, as shown in Figure 1a.wt.%) was prepared.The PBF-LB/M process was employed to form the components, followed by a comprehensive analysis of their microstructure, phase composition, and mechanical properties.

Materials and Powder Preparation
In this study, the raw material for the A2024 aluminum alloy powder was prepared using the gas atomization method.Table 1 outlines the chemical components of this powder, which exhibit a regular spherical shape and a typical unimodal particle size distribution, as shown in Figure 1a.The measured values for D10, D50, and D90 are 18.84 µm, 37.62 µm, and 50.07 µm, respectively, as shown in To enhance the performance of the alloy, scientifically graded LaB6 powders with particle sizes close to 50 nm and relatively irregular morphology were added.As shown in Figure 1b, these powders were mechanically mixed with the A2024 powder in an argon environment using a ball mill.The grinding conditions were optimized at a speed of 300 rpm, a duration of 160 min, and a ball-material ratio of 2:1.The LaB6 powder was added The measured values for D10, D50, and D90 are 18.84 µm, 37.62 µm, and 50.07 µm, respectively, as shown in Figure 2 wt.%) was prepared.The PBF-LB/M process was employed to form the components, followed by a comprehensive analysis of their microstructure, phase composition, and mechanical properties.

Materials and Powder Preparation
In this study, the raw material for the A2024 aluminum alloy powder was prepared using the gas atomization method.Table 1 outlines the chemical components of this powder, which exhibit a regular spherical shape and a typical unimodal particle size distribution, as shown in Figure 1a.To enhance the performance of the alloy, scientifically graded LaB6 powders with particle sizes close to 50 nm and relatively irregular morphology were added.As shown in Figure 1b, these powders were mechanically mixed with the A2024 powder in an argon environment using a ball mill.The grinding conditions were optimized at a speed of 300 rpm, a duration of 160 min, and a ball-material ratio of 2:1.The LaB6 powder was added To enhance the performance of the alloy, scientifically graded LaB 6 powders with particle sizes close to 50 nm and relatively irregular morphology were added.As shown in Figure 1b, these powders were mechanically mixed with the A2024 powder in an argon environment using a ball mill.The grinding conditions were optimized at a speed of 300 rpm, a duration of 160 min, and a ball-material ratio of 2:1.The LaB 6 powder was added in varying amounts: 0.25, 0.5, 0.75, and 1.0 weight%.This approach was used to explore the influence of reinforcement phase contents on the microstructure, phase composition, and mechanical properties of the resulting materials processed via PBF-LB/M.
For the purposes of simplification, the printed LaB 6 /A2024 samples were designated as S 0 , S 0.2 , S 0.5 , S 0.75 , and S 1 , corresponding to the varying reinforcement phase contents of the LaB 6 powder.Figure 1c demonstrates that the microstructure of the LaB 6 /A2024 mixed powder remains intact after ball milling, indicating no significant agglomeration or particle growth.Prior to the laser powder bed fusion (PBF-LB/M) process, all raw material powders were vacuum-dried at 100 • C for 8 h to eliminate any moisture content and ensure consistent fusion during the printing process.The corresponding EDS plot in Figure 1d further indicates the successful mixing of the sample.

Laser Powder Bed Fusion Processing
In this study, the required samples were manufactured using laser powder bed fusion (PBF-LB/M) technology on an XDM 120 machine equipped with a Yb 5500 W IPG fiber laser.The A2024 platform was selected as the building base for all samples, and the substrate was preheated to 200 • C to ensure optimal adhesion and minimize thermal stress during the printing process.To prevent oxidation and maintain the integrity of the printed parts, stringent measures were implemented to limit the oxygen content in the forming chamber to below 50 ppm throughout the PBF-LB/M process.These measures included the use of inert gases and a closed-loop oxygen control system to ensure high-quality printed samples.
After careful optimization, the laser processing parameters were determined as follows: a laser power of 300 W, a scanning speed of 1300 mm/s, a pattern spacing of 120 µm, and a layer thickness of 30 µm.Additionally, a scanning rotation angle of 67 • was employed between each layer to enhance mechanical performance and minimize anisotropy.These parameters were chosen to optimize the fusion quality, material distribution, and overall mechanical properties of the printed samples.Figure 3a actually depicts the scanning strategy employed during the PBF-LB/M process, illustrating the application of the optimized laser processing parameters. in varying amounts: 0.25, 0.5, 0.75, and 1.0 weight%.This approach was used to explore the influence of reinforcement phase contents on the microstructure, phase composition, and mechanical properties of the resulting materials processed via PBF-LB/M.For the purposes of simplification, the printed LaB6/A2024 samples were designated as S0, S0.2, S0.5, S0.75, and S1, corresponding to the varying reinforcement phase contents of the LaB6 powder.Figure 1c demonstrates that the microstructure of the LaB6/A2024 mixed powder remains intact after ball milling, indicating no significant agglomeration or particle growth.Prior to the laser powder bed fusion (PBF-LB/M) process, all raw material powders were vacuum-dried at 100 °C for 8 h to eliminate any moisture content and ensure consistent fusion during the printing process.The corresponding EDS plot in Figure 1d further indicates the successful mixing of the sample.

Laser Powder Bed Fusion Processing
In this study, the required samples were manufactured using laser powder bed fusion (PBF-LB/M) technology on an XDM 120 machine equipped with a Yb 5500 W IPG fiber laser.The A2024 platform was selected as the building base for all samples, and the substrate was preheated to 200 °C to ensure optimal adhesion and minimize thermal stress during the printing process.To prevent oxidation and maintain the integrity of the printed parts, stringent measures were implemented to limit the oxygen content in the forming chamber to below 50 ppm throughout the PBF-LB/M process.These measures included the use of inert gases and a closed-loop oxygen control system to ensure high-quality printed samples.
After careful optimization, the laser processing parameters were determined as follows: a laser power of 300 W, a scanning speed of 1300 mm/s, a pattern spacing of 120 µm, and a layer thickness of 30 µm.Additionally, a scanning rotation angle of 67° was employed between each layer to enhance mechanical performance and minimize anisotropy.These parameters were chosen to optimize the fusion quality, material distribution, and overall mechanical properties of the printed samples.Figure 3a actually depicts the scanning strategy employed during the PBF-LB/M process, illustrating the application of the optimized laser processing parameters.To explore the material's characteristics, we printed multiple cubes (10 × 10 × 5 mm 3 ) and tensile bars following the ASTM E8 standard [36].The tensile bars had a gauge length of 19.6 mm, a width of 5 mm, and a thickness of 2 mm, as illustrated in Figure 1b.
To ensure the reproducibility and consistency of the experimental results, three sets of replicate samples were fabricated under identical conditions.

Microstructural Characterization
The microstructure was analyzed using standardized techniques, which involved chemical etching at room temperature.The etching solution comprised 95 mL H2O, 2.5 To explore the material's characteristics, we printed multiple cubes (10 × 10 × 5 mm 3 ) and tensile bars following the ASTM E8 standard [36].The tensile bars had a gauge length of 19.6 mm, a width of 5 mm, and a thickness of 2 mm, as illustrated in Figure 1b.
To ensure the reproducibility and consistency of the experimental results, three sets of replicate samples were fabricated under identical conditions.

Microstructural Characterization
The microstructure was analyzed using standardized techniques, which involved chemical etching at room temperature.The etching solution comprised 95 mL H 2 O, 2.5 mL HNO 3 , 1.5 mL HCl, and 1 mL HF per 100 mL of the solution.Microstructure characterization was conducted using a scanning electron microscope (SEM, FEI Nova Nano SEM 450, Hillsboro, OR, USA) equipped with an energy dispersive spectroscopy (EDS, Oxford X-Max 50, Shanghai, China) system.The phase identification of feedstock powders and specimens was performed using X-ray diffraction (XRD-D8 Advance, Beijing, China) with Cu-Kα radi-ation at 40 kV and 30 mA, employing a speed of 2 • /min and scanning angle range of 20-90 • .The grain size, morphology, and texture of each as-built sample were assessed through electron backscatter diffraction (EBSD).Furthermore, transmission electron microscopy (TEM; JEM-2100F, Changsha, China) was employed for detailed phase observation.

Mechanical Testing
The microhardness of the sample was evaluated on the polished XY plane using a Vickers hardness tester (HVS-1000ZCM-XY, Wuxi, China).A 200 g load was applied for 15 s, and ten indentations were randomly made on each sample.The average microhardness and standard deviation were then calculated.Room temperature tensile tests were carried out using an electronic universal testing machine (WDW-100KN, provided by Jinan Sida Testing Technology Co., Ltd., Wuxi, China) with an extensometer.The tensile rate was set at 0.5 mm/min, and three specimens from each sample group were tested, with the results averaged to determine a mean value.

Phase Analysis
The XRD pattern in Figure 4 displays the phase analysis of the powder and an XY cross-section of the PBF-LB/M samples.
terization was conducted using a scanning electron microscope (SEM, FEI Nova Nano SEM 450, Hillsboro, OR, USA) equipped with an energy dispersive spectroscopy (EDS, Oxford X-Max 50, Shanghai, China) system.The phase identification of feedstock powders and specimens was performed using X-ray diffraction (XRD-D8 Advance, Beijing, China) with Cu-Kα radiation at 40 kV and 30 mA, employing a speed of 2°/min and scanning angle range of 20-90°.The grain size, morphology, and texture of each as-built sample were assessed through electron backscatter diffraction (EBSD).Furthermore, transmission electron microscopy (TEM; JEM-2100F, Changsha, China) was employed for detailed phase observation.

Mechanical Testing
The microhardness of the sample was evaluated on the polished XY plane using a Vickers hardness tester (HVS-1000ZCM-XY, Wuxi, China).A 200 g load was applied for 15 s, and ten indentations were randomly made on each sample.The average microhardness and standard deviation were then calculated.Room temperature tensile tests were carried out using an electronic universal testing machine (WDW-100KN, provided by Jinan Sida Testing Technology Co., Ltd., Wuxi, China) with an extensometer.The tensile rate was set at 0.5 mm/min, and three specimens from each sample group were tested, with the results averaged to determine a mean value.

Phase Analysis
The XRD pattern in Figure 4 displays the phase analysis of the powder and an XY cross-section of the PBF-LB/M samples.It is observed that the peak intensities of some phases, such as α-Al, in the PBF-LB/M samples are generally lower compared to the initial powder, while other phases, like Al2CuMg, may exhibit comparable or even higher peak intensities.The PBF-LB/M-formed alloys primarily comprised face-centered cubic (fcc) α-Al with main orientations at (111), ( 200), (220), and (311).LaB6 peaks are not detected at the current XRD resolution due to the low addition amounts.Notably, the relative intensity of the α-Al Bragg's peak remains consistent with respect to the increasing LaB6 amounts and no new phase is observed, indicating the high stability of the LaB6 nanoparticles.Apart from α-Al, which is the main phase, the intermetallic phases of Al2Cu, Al2CuMg, and Al3Mg2 are also present.It is observed that the peak intensities of some phases, such as α-Al, in the PBF-LB/M samples are generally lower compared to the initial powder, while other phases, like Al 2 CuMg, may exhibit comparable or even higher peak intensities.The PBF-LB/M-formed alloys primarily comprised face-centered cubic (fcc) α-Al with main orientations at (111), ( 200), (220), and (311).LaB 6 peaks are not detected at the current XRD resolution due to the low addition amounts.Notably, the relative intensity of the α-Al Bragg's peak remains consistent with respect to the increasing LaB 6 amounts and no new phase is observed, indicating the high stability of the LaB 6 nanoparticles.Apart from α-Al, which is the main phase, the intermetallic phases of Al 2 Cu, Al 2 CuMg, and Al 3 Mg 2 are also present.

Microstructure Analysis
Figure 5 presents the SEM morphology of the microstructure of the LaB 6 /A2024 alloy fabricated via PBF-LB/M.For sample preparation, the LPBF-formed samples were polished using standard metallographic techniques and etched with Keller's reagent (HF:HCl:HNO 3 :H 2 O = 1:1.5:2.5:95) to reveal the microstructure.

Microstructure Analysis
Figure 5 presents the SEM morphology of the microstructure of the LaB6/A2024 alloy fabricated via PBF-LB/M.For sample preparation, the LPBF-formed samples were polished using standard metallographic techniques and etched with Keller's reagent (HF:HCl:HNO3:H2O = 1:1.5:2.5:95) to reveal the microstructure.It is evident that the addition of the heterogeneous nucleating agent LaB6 effectively mitigates crack defects in the PBF-LB/M-formed A2024.As shown in Figure 5a, the high thermal sensitivity of A2024 leads to severe cracking during rapid solidification.However, in the S1 sample, the cracks are mainly attributed to the agglomeration caused by the high content present in the reinforcement phase, which intensifies the stress concentration during the forming process.In the S0.25, S0.5, and S0.75 samples, the crack's density significantly decreases.By performing comparisons in Figure 5, it can be observed that the pores in S0 are more obvious, with a significant reduction in pores at S0.25, S0.5, and S0.75.Based on experimental observations, porosity seems to have decreased and a more significant change was observed in S0.5 porosity.At this point, the second phases, LaB6 and α-, were observed.There are small differences in the atomic arrangement between different crystal structures in Al solid solutions, which helps to form coherent or semi-coherent interfaces.This results in α-.The nucleation barrier of the Al phase is relatively low, resulting in small equiaxed grains.α-Al grains are more adaptable to strain than hard, coarse columnar grains [37].Moreover, the increase in the total grain boundary area per unit volume of metal reduces the thickness of its residual liquid film, preventing the initiation and propagation of cracks.
Figure 5 illustrates that both the A2024 aluminum alloy and its composites exhibit a typical equiaxed grain structure.In comparison to traditional casting or forging processes, the PBF-LB/M samples produce smaller equiaxed grain.While all samples display an interconnected grain boundary network, sample S0 without LaB6 nanoparticles not only has coarser grains but also exhibits unclear grain boundary regions.With the addition of LaB6, It is evident that the addition of the heterogeneous nucleating agent LaB 6 effectively mitigates crack defects in the PBF-LB/M-formed A2024.As shown in Figure 5a, the high thermal sensitivity of A2024 leads to severe cracking during rapid solidification.However, in the S1 sample, the cracks are mainly attributed to the agglomeration caused by the high content present in the reinforcement phase, which intensifies the stress concentration during the forming process.In the S 0.25 , S 0.5 , and S 0.75 samples, the crack's density significantly decreases.By performing comparisons in Figure 5, it can be observed that the pores in S0 are more obvious, with a significant reduction in pores at S 0.25 , S 0.5 , and S 0.75 .Based on experimental observations, porosity seems to have decreased and a more significant change was observed in S 0.5 porosity.At this point, the second phases, LaB 6 and α-, were observed.There are small differences in the atomic arrangement between different crystal structures in Al solid solutions, which helps to form coherent or semi-coherent interfaces.This results in α-.The nucleation barrier of the Al phase is relatively low, resulting in small equiaxed grains.α-Al grains are more adaptable to strain than hard, coarse columnar grains [37].Moreover, the increase in the total grain boundary area per unit volume of metal reduces the thickness of its residual liquid film, preventing the initiation and propagation of cracks.
Figure 5 illustrates that both the A2024 aluminum alloy and its composites exhibit a typical equiaxed grain structure.In comparison to traditional casting or forging processes, the PBF-LB/M samples produce smaller equiaxed grain.While all samples display an interconnected grain boundary network, sample S 0 without LaB 6 nanoparticles not only has coarser grains but also exhibits unclear grain boundary regions.With the addition of LaB 6 , significant grain refinement and clear grain boundaries can be observed in S 0.25 and S 0.5 samples.The characteristics of the gray cells in the microstructure of PBF-LB/M samples all represent supersaturated primary α-Al.A partial magnification of Figure 5c-1 reveals that precipitates gather near grain boundaries, and the grain consists of numerous cellular dendrites, with dendrite arm spacing measuring 1~2 µm.It is worth noting that due to the morphological changes in the second phase of the melt pool, a flat melting boundary area can be found on the surface of the sample, and there are large dendrites distributed in the interface area.This can be attributed to the different cooling rates at different positions within the PBF-LB/M melt pool [38], as shown in Figure 5d.

Grain Morphology Evolution
Figure 6 illustrates the EBSD-IPF diagrams along with their corresponding pole diagrams for all PBF-LB/M-formed alloys at XY cross-sections.
significant grain refinement and clear grain boundaries can be observed in S0.25 and S0.5 samples.The characteristics of the gray cells in the microstructure of PBF-LB/M samples all represent supersaturated primary α-Al.A partial magnification of Figure 5c-1 reveals that precipitates gather near grain boundaries, and the grain consists of numerous cellular dendrites, with dendrite arm spacing measuring 1~2 µm.It is worth noting that due to the morphological changes in the second phase of the melt pool, a flat melting boundary area can be found on the surface of the sample, and there are large dendrites distributed in the interface area.This can be attributed to the different cooling rates at different positions within the PBF-LB/M melt pool [38], as shown in Figure 5d.

Grain Morphology Evolution
Figure 6 illustrates the EBSD-IPF diagrams along with their corresponding pole diagrams for all PBF-LB/M-formed alloys at XY cross-sections.The grain size distribution, average grain size, dislocation angle, and GND density of all samples were derived from the EBSD-IPF diagram, as presented in Figure 7.The grain size distribution, average grain size, dislocation angle, and GND density of all samples were derived from the EBSD-IPF diagram, as presented in Figure 7. Notably, the S0 samples exhibit pronounced microstructural heterogeneity, characterized by a mixture of course-length columnar crystals and equiaxed crystals.While the proportion of equiaxed grains is relatively small, they exhibit random orientations.However, as opposed to the distribution of equiaxed grains, the color of columnar crystals in Notably, the S 0 samples exhibit pronounced microstructural heterogeneity, characterized by a mixture of course-length columnar crystals and equiaxed crystals.While the proportion of equiaxed grains is relatively small, they exhibit random orientations.However, as opposed to the distribution of equiaxed grains, the color of columnar crystals in the sample is predominantly red, indicating that the crystal orientation of these grains is mainly (001), with the fiber texture being <001>.The corresponding pole figure (PF) indicates a maximum texture index of 3.39.Numerous intergranular solidification cracks are distributed on the samples' surface, penetrating through the entire grain, with the widest crack measuring approximately 14.1 µm, consistent with previous studies on the solidification crack behavior of PBF-LB/M-formed alloys [28,39].
LaB 6 particles refined the grain sizes and caused a columnar to equiaxed (CET) structural transformation.By introducing 0.5 wt.% LaB 6 , the average grain size was reduced by 12.62% compared to that of the S 0 alloy, decreasing it from 10.3 µm to a smaller size.This reduction in grain size increased the number of grain boundaries, promoting a more uniform distribution of residual stress at these boundaries.Consequently, the material's crack sensitivity was reduced.Furthermore, a closer examination of the pole figure reveals a slight enhancement in the texture strength of S 0.5 with increasing LaB 6 content.
Figure 6c,f depict the KAM distribution of the two alloys.Near the grain boundary, the orientation deviation is approximately 2 • , while within the grain, it is around 0 • .Higher KAM values and nuclei with higher KAM values cluster near the solidification crack of the A2024 alloy.The required geometric dislocation density distribution diagram (GND) is shown in Figure 6c,f, and it reveals that the average GND density increases from 3.9 × 10 14 m −2 to 4.1 × 10 14 m −2 after adding the enhanced phase.This indicates that the addition of a reinforcing phase increases the dislocation density in the matrix, thereby enhancing the effect of dislocation reinforcement and helping to improve strength.

Mechanical Properties Evolution
From Figure 8a, it can be seen that the hardness of the sample increases with an increase in LaB 6 content.Room temperature tensile tests were performed on all samples to assess how the LaB6 content influences the mechanical characteristics of aluminum matrix composites.The findings, summarized in Table 2, are visually represented in Figure 8b.Room temperature tensile tests were performed on all samples to assess how the LaB 6 content influences the mechanical characteristics of aluminum matrix composites.The findings, summarized in Table 2, are visually represented in Figure 8b.This figure specifically highlights the impact of LaB 6 content on the following tensile parameters: the yield strength (YS) of the stress limit for the yield phenomenon of metals under external forces; the maximum stress values that metal materials can withstand during the tensile process, namely the fracture strength and ultimate tensile strength (UTS); and the elongation rate (A) of the deformation range that metal materials can withstand under tensile force.Notably, the LaB 6 content emerges as a significant factor in determining each of these tensile attributes.It can be seen that, due to the significant forming issues, both the S 0 and S 1 samples exhibit numerous cracks, resulting in limited strength.With a further increase in LaB 6 content to 0.25 wt.%, YS (125 ± 8 MPa), UTS (177 ± 3 MPa), and A (0.67 ± 0.26) increased by 115.52%, 205.17%, and 204.55%, respectively, compared with S 0 .However, among all alloy systems, the sample with 0.5 wt.% LaB 6 (S 0.5 ) demonstrates the best overall performance in terms of YS, UTS, and A. Nonetheless, its elongation is only 1.58%, indicating the persistence of certain challenges in the S 0.5 samples, which is consistent with the EBSD detection results described earlier.

Densification Behavior
This study has confirmed the effectiveness of LaB 6 as a heterogeneous nucleating agent in the preparation of A2024 alloys using PBF-LB/M.The addition of 0.5 wt.% of LaB 6 nanoparticles to high-strength aluminum alloys has been shown to decrease crack formation, improve machinability, and inhibit pore formation.
An excellent powder bed with spherical particles, good fluidity, and high powder quality was obtained by incorporating nano-LaB 6 into the initial powder through an effective mechanical ball milling method.The presence of non-oxidized ceramics in the powder bed significantly alters the machinability of the A2024 alloy prepared using PBF-LB/M.This change is attributed to nano-LaB 6 's high laser absorption rate and the dense powder bed's ability to enhance the multiple reflection effect of the laser [40][41][42].Together, these factors effectively address the processing challenges caused by the high reflectivity of aluminum alloy.The microstructure analysis of various samples reveals the presence of numerous pores and cracks within the A2024 aluminum alloy.These defects are primarily due to the inadequate melting of powder particles resulting from high reflectivity, insufficient liquid supply during solidification, and the poor flowability of low-viscosity melt.
The addition of 0.5 wt.% LaB 6 nanoparticles to A2024 aluminum alloy has been found to enhance the machinability of the composite material.This improvement is attributed to the higher melt viscosity of the 0.5 wt.% LaB 6 /A2024 composite, which hinders Marangoni flow and minimizes spatter formation, resulting in improved formability.Despite the local molten pool temperature in the PBF-LB/M process, which exceeds the high melting point of LaB 6 (2988 K), the analysis in Figure 4 indicates that no new substances similar to Al-La and Al-B are formed in the composite material.The unreacted LaB 6 nanoparticles play a key role in increasing the overall viscosity of the molten pool, enabling the rapid filling of defects and thereby reducing pore formation and suppressing crack formation.

Grain Refinement by LaB 6 Nanoparticles
After the addition of nano-LaB 6 particles, the grain sizes of the S 0 sample and S 0.5 composite are 10.3 µm and 9.0 µm, respectively (Figure 7a,d), representing a reduction of 12.6%.Nano-LaB 6 particles demonstrate high stability and act as effective heterogeneous nucleating agents, increasing the nucleation probability during the alloy's melting and solidification process.This promotes the formation of uniformly fine equiaxial grains from the original columnar grains in the PBF-LB/M component, leading to a decrease in grain size.Additionally, the coherent interface with a small lattice mismatch between LaB 6 particles and α-Al facilitates their dissolution in the matrix melt, promoting the heterogeneous nucleation of Al [43].Moreover, the significant Marangoni effect causes LaB 6 particles to accumulate in the grain boundary region, hindering grain epitaxy growth.The combination of these mechanisms results in a significant reduction in the sample's grain size (Figure 9) [44].
and Al-B are formed in the composite material.The unreacted LaB6 nanoparticles play a key role in increasing the overall viscosity of the molten pool, enabling the rapid filling of defects and thereby reducing pore formation and suppressing crack formation.

Grain Refinement by LaB6 Nanoparticles
After the addition of nano-LaB6 particles, the grain sizes of the S0 sample and S0.5 composite are 10.3 µm and 9.0 µm, respectively (Figure 7a,d), representing a reduction of 12.6%.Nano-LaB6 particles demonstrate high stability and act as effective heterogeneous nucleating agents, increasing the nucleation probability during the alloy's melting and solidification process.This promotes the formation of uniformly fine equiaxial grains from the original columnar grains in the PBF-LB/M component, leading to a decrease in grain size.Additionally, the coherent interface with a small lattice mismatch between LaB6 particles and α-Al facilitates their dissolution in the matrix melt, promoting the heterogeneous nucleation of Al [43].Moreover, the significant Marangoni effect causes LaB6 particles to accumulate in the grain boundary region, hindering grain epitaxy growth.The combination of these mechanisms results in a significant reduction in the sample's grain size (Figure 9) [44].To further investigate the incorporation of LaB 6 into A2024 and examine the Cu-coated LaB 6 interface, a sample was thinned using the focused ion beam (FIB) technique, as illustrated in Figure 10.To further investigate the incorporation of LaB6 into A2024 and examine the Cucoated LaB6 interface, a sample was thinned using the focused ion beam (FIB) technique, as illustrated in Figure 10.The diffraction pattern reveals that the outer white region corresponds to A2024 aluminum alloys, while the black area represents copper-coated nano-LaB6.Additionally, Figure 10 showcases the lattice transmission electron microscopy (TEM) and selected area electron diffraction (SAED) images of 0.5 wt.% LaB6/A2024 composites.In Figure 10k, the The diffraction pattern reveals that the outer white region corresponds to A2024 aluminum alloys, while the black area represents copper-coated nano-LaB 6 .Additionally, Figure 10 showcases the lattice transmission electron microscopy (TEM) and selected area electron diffraction (SAED) images of 0.5 wt.% LaB 6 /A2024 composites.In Figure 10k, the LaB 6 unit cells are uniformly arranged without growth defects, with a measured unit cell distance of approximately 2.77 Å [45].Moreover, large crystal cells attributed to Cu atoms are visible on the sample surface.The diffraction spots post-Fourier transform are depicted in Figure 10l, indicating the cubic nature of LaB 6 .The interplanar spacing of the lattice fringes measures 2.77 corresponding to the (110) crystal plane spacing.These observations suggest robust interfacial adhesion between Cu and LaB 6 , resulting in the accumulation of LaB 6 nanoparticles near Cu atoms at grain boundaries, which act as nucleation stabilizers through the Zener-pin effect and microstructural stabilizers.Furthermore, an increase in dislocation density at the LaB 6 -A2024 matrix interface enhances mechanical properties.

Mechanical Properties
The strengthening mechanisms of LaB 6 /A024 metal matrix composites (MMCs) prepared via PBF-LB/M can be categorized into four groups: fine-grain strengthening mechanism, load-transfer strengthening mechanism, dislocation strengthening mechanism, and Orowan strengthening mechanism, each operating independently.The yield strength is influenced by the combined contribution of all four mechanisms: 1.
Fine-grain strengthening: The fine grains of PBF-LB/M-prepared A2024 composites are critical in determining their properties.The incorporation of LaB 6 reinforcement particles provides extra nucleation points, aiding in the formation of the matrix phase and hindering grain growth.According to the Hall-Petch relation, materials exhibit increased strength as grain size decreases.Alloys with smaller grains generally have higher strength [45,46].Moreover, the addition of reinforcement particles can enhance the ductility of metal matrix composites (MMCs).However, there is a limit to grain refinement, and an optimal amount of reinforcement particles is required for peak performance.This explains why the performance of S 0.75 is not as good as that of S 0.5 .Furthermore, the high thermal conductivity of LaB 6 particles speeds up heat dissipation in the molten pool, resulting in improved cooling rates and the formation of LaB 6 /A2024 composites: where d 0 is the grain size of the raw material, and k y is a constant related to the material.

2.
Load-transfer strengthening occurs in PBF-LB/M-prepared LaB 6 /A2024 composites when external forces are applied, with nanoparticles at grain boundaries showing strong bonding properties.This facilitates load transfers and increases the composite's strength [22,47].Additionally, the application of loads improves the microhardness of the composite by preventing material plastic deformation due to dislocations between the matrix phase and LaB 6 particles [23,48].The strong interface bond between reinforced particles and the matrix promotes effective load transfers, ultimately enhancing the composite's strength: where σ m is the strength of the raw material.

3.
Dislocation strengthening in composite materials is a result of mismatched thermal expansion and elastic modulus between the matrix and reinforcing particles.This mismatch becomes more significant at elevated temperatures, resulting in an increase in residual plastic strain and dislocation density.The improvement in the mechanical properties of composites is attributed to the dislocation density arising from the mismatch in thermal expansion coefficients.The relationship between dislocation density and the strength of composite materials can be described using the following formula [49][50][51]: The formula for dislocation strengthening includes a constant β of approximately 1.25; the shear modulus of the matrix G m ; the Burger's vector magnitude b; the particle content v p ; the size of equiaxed particles d p ; the difference in thermal expansion ∆C; and the temperature difference ∆T between ambient and processing temperatures.4.
When dislocations evade small strengthening particles, Orowan strengthening occurs.These particles serve as anchor points for dislocations, causing them to bend when subjected to external forces.This hinders the movement of dislocations and ultimately boosts the strength of metal matrix composites (MMCs) [51].This process, known as Orowan strengthening, has been demonstrated in studies to be achievable only with small reinforcing particles (<1 µm) [49].The transmission electron microscopy (TEM) images in this research on PBF-LB/M-fabricated LaB 6 /A2024 composites clearly display a uniform distribution of nanoscale LaB 6 particles within the matrix, as depicted in Figure 10.Orowan strengthening plays a vital role in enhancing the strength of iron-based MMCs reinforced with particles and fabricated using the PBF-LB/M technique.This strengthening mechanism can be mathematically described using the following formula [51][52][53]: M, G m , b, and v represent the Taylor factor, shear modulus of the matrix material, Burger's vector, and Poisson's ratio, respectively.L indicates the interparticle spacing, while d p and v p represent the size and volume fraction of the reinforced particles.
This study shows that finely dispersed LaB 6 particles effectively hinder the motion of dislocations, leading to an increase in the yield strength of A2024 aluminumbased composites.

Conclusions
In this study, we investigated the microstructure and mechanical properties of LaB 6 /A024 alloys produced using the PBF-LB/M process.The main findings are as follows: 1.
In comparison to the unmodified A2024 alloy, the A2024 alloy modified with LaB 6 exhibits an improvement in PBF-LB/M workability, leading to substantial reductions in porosity and solidification cracking.2.
Adding 0.5 wt.% LaB 6 resulted in a transformation of the microstructure of the composite material into a single, uniform, equiaxed structure, with a refined grain size of 9.0 µm.Compared with the coarse and long columnar structure of traditional A2024 alloys, this uniform isomeric crystal structure significantly improves the solidification cracking resistance of the composite material.The improvements in this microstructure provide valuable insights into improving the overall performance and reliability of composite materials in practical applications.

3.
The positive coating interaction between cubic ceramic nanoparticles and copper atoms (beneficial interface interaction between nanoparticles and matrix metal) highlights the significant efficacy of LaB 6 as a non-uniform grain refiner for aluminum.A large portion of LaB 6 nanoparticles is concentrated in the liquid phase during grain development, acting as microstructural stabilizers at grain boundaries through the Zener pinning mechanism.4.
The tensile strength of A2024 alloy is between 300 and 400 MPa, and the elongation is between 5 and 10%.However, these values may vary due to different preparation processes, heat treatment conditions, and alloy compositions.The tension strength and elongation at the frame of the A2024 alloy modified with 0.5 wt.% LaB 6 are 251 ± 2 MPa and 1.58 ± 0.12%, respectively.

Figure 1 .
Figure 1.The morphology of feedstock powder: (a) the micrograph of A2024 powder, (b) the micrograph of LaB6 powder, (c) the micrograph of LaB6/A2024 mixed powder, and (d) the corresponding EDS maps of (c).

Figure 1 .
Figure 1.The morphology of feedstock powder: (a) the micrograph of A2024 powder, (b) the micrograph of LaB 6 powder, (c) the micrograph of LaB 6 /A2024 mixed powder, and (d) the corresponding EDS maps of (c).

Figure 1 .
Figure 1.The morphology of feedstock powder: (a) the micrograph of A2024 powder, (b) the micrograph of LaB6 powder, (c) the micrograph of LaB6/A2024 mixed powder, and (d) the corresponding EDS maps of (c).

Figure 3 .
Figure 3. (a) Scanning strategy between consecutive layers and (b) tensile specimen details.

Figure 3 .
Figure 3. (a) Scanning strategy between consecutive layers and (b) tensile specimen details.

Figure 4 .
Figure 4. X-ray diffraction patterns of A2024 powder and constructed PBF-LB/M samples: (a) complete XRD patterns within the range of 20~90°; and (b) the amplified area of the pattern, representing low intensities.

Figure 4 .
Figure 4. X-ray diffraction patterns of A2024 powder and constructed PBF-LB/M samples: (a) complete XRD patterns within the range of 20~90 • ; and (b) the amplified area of the pattern, representing low intensities.

Figure 6 .
Figure 6.Horizontal EBSD inverse pole plot (EBSD-IPF): pole plots of (a-c) S0, (d-f) S0.5, and KAM.Observe the crystal orientation along the top surface (XY plane) and the IPF color of the sample, including the code representing the grain orientation.The KAM mapping is retrieved in degrees from the EBSD-IPF mapping in a,d.

Figure 6 .
Figure 6.Horizontal EBSD inverse pole plot (EBSD-IPF): pole plots of (a-c) S 0 , (d-f) S 0.5 , and KAM.Observe the crystal orientation along the top surface (XY plane) and the IPF color of the sample, including the code representing the grain orientation.The KAM mapping is retrieved in degrees from the EBSD-IPF mapping in (a,d).

Figure 7 .
Figure 7. Average grain size of the PBF-LB/M-formed alloys.(a) S 0 and (b) S 0.5 ; misorientation angle of (d) S 0 and (e) S 0.5 ; and GND density of (c) S 0 and (f) S 0.5 .

Figure 8 .
Figure 8.The mechanical properties of LaB 6 /A2024 samples prepared by LPFB.(a) Microhardness and (b) tensile performance.The hardness values of S 0.25 , S 0.5 , and S 0.75 are 109.1 ± 4.2, 124.2 ± 4.4, and 130.6 ± 4.3 HV 0.2 , respectively.These values represent increases of 44.31%, 64.29%, and 72.75% compared to the hardness of S 0 samples, which measured 75.6 ± 3.6 HV 0.2 .Notably, sample S 1 exhibits the highest hardness at 135.0 ± 3.3 HV 0.2 , representing a remarkable increase of 78.57% compared to S 0 .Room temperature tensile tests were performed on all samples to assess how the LaB 6 content influences the mechanical characteristics of aluminum matrix composites.The findings, summarized in Table2, are visually represented in Figure8b.

Figure 9 .
Figure 9.The formation mechanism and morphology of A2024 composite alloys during the PBF-LB/M process: (a) A2024 and (b) A2024 with LaB6 particle addition.

Figure 9 .
Figure 9.The formation mechanism and morphology of A2024 composite alloys during the PBF-LB/M process: (a) A2024 and (b) A2024 with LaB 6 particle addition.

Table 2 .
Mechanical properties of the PBF-LB/M as-built specimens.

Table 2 .
Mechanical properties of the PBF-LB/M as-built specimens.